Lanthanides,9783540645269

Lanthanides

by ; ; ; ; ; ;
ISBN13: 9783540645269
ISBN10: 3540645268
Format: Hardcover
Pub. Date: 1999-03-01
Publisher(s): Springer Verlag
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Summary

The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistryis designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.

Table of Contents

Principles in Organolanthanide Chemistry
1(62)
R. Anwander
Lanthanide Triflate-Catalyzed Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
63(56)
S. Kobayashi
Lanthanide- and Group 3 Metallocene Catalysis in Small Molecule Synthesis
119(36)
G. Molander
E. C. Dowdy
Influence of Solvents or Additives on the Organic Chemistry Mediated by Diiodosamarium
155(44)
H. Kagan
J.L. Namy
Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifuncational Catalysts for the Asymmetric Formation of C-C, C-O and C-P Bonds
199(34)
M. Shibasaki
H. Groger
Reactions of Ketones with Low-Valent Lanthanides: Isolation and Reactivity of Lanthanide Ketyl and Ketone Dianion Complexes
233(22)
Z. Hou
Y. Wakatsuki
Organo Rare Earth Metal Catalysis for the Living Polymerizations of Polar and Nonpolar Monomers
255(30)
H. Yasuda
Polymer-Supported Rare Earth Catalysts Used in Organic Synthesis
285(22)
S. Kobayashi
Author Index 307

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