Organic/Inorganic Hybrid Materials II: Materials Research Society Symposium Proceedings, Held April 5-9, 1999, Sanfrancisco, California, U.S.A.

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Edition: 1st
Format: Hardcover
Pub. Date: 2000-01-01
Publisher(s): Cambridge Univ Pr
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Summary

The rapidly growing interest in novel low-temperature, solution-based synthesis of functional materials is reflected in this volume from the Materials Research Society. A recurring theme of the book is 'materials design.' The great versatility of organic/inorganic hybrids lies in the range of properties afforded by the combination of organic and inorganic constituents, and in the multiple length scales - from atomic, through molecular and mesoscopic, to micro- and macroscopic - over which the chemical interactions and structure of the materials may be controlled. Reflecting the symposium's origins in the Better Ceramics Through Chemistry series of the late 1980s and early 1990s, a significant number of papers deal with the chemistry of salines and other organometallic compounds. Topics include: synthesis and processing; novel ordered hybrid structures, layered structures and organic monolayers; nonsilicate hybrid materials; meso-, micro- and macroporous hybrids; hybrid electrochemistry, photochemistry and passivation; mechanical properties and applications; and biomedical, electronic and optical applications of hybrid materials.

Table of Contents

Preface xi
Materials Research Society Symposium Proceedings xii
PART I: SYNTHESIS AND PROCESSING
Organic/Inorganic Molecular Hybrid Materials From Cubic Silsesquioxanes
3(12)
R.M. Laine
M. Asuncion
S. Ballat
N.L. Dias Filho
J. Harcup
A.C. Sutorik
L. Viculis
A.F. Yee
C. Zhang
Q. Zhu
Malemide Functionalized Siloxane Resins
15(6)
R.M. Shaltout
D.A. Loy
D.R. Wheeler
Characterization of Organically Modified Silicates by 17O Solid State MAS and MQ-MAS NMR
21(6)
V. Gualandris
J. Maquet
F. Babonneau
P. Florian
D. Massiot
Storage Stability of Solvent-Free Condensates of Functionalized Trialkoxysilanes
27(6)
S. Stein
St.C.V. Clausbruch
N. Moszner
V. Rheinberger
Preparation and Properties of Inorganic-Organic Hybrids From Vinyl- and 3-Methacryloxypropyltrimethoxysilane
33(6)
N. Takamura
T. Gunji
Y. Abe
X-ray and Neutron Small Angle Scattering Investigations on Precursor Derived B-C-N Ceramics
39(6)
D. Sauter
S. Schempp
M. Weinmann
A. Muller
J. Bill
P. Lamparter
F. Aldinger
Organic-Inorganic Hybrid Materials From Surface Initiated Polymerization
45(6)
T.A.P. Seery
F. Vatansever
Different Solvent Free Synthetic Routes to Organic/Inorganic Hybrid Materials
51(12)
H. Kaddami
J.F. Gerard
J.P. Pascault
Sol-Gel Chemistry by Ring-Opening Polymerization
63(6)
K. Rahimian
D.A. Loy
Dendrimer-Metal Nancomposites
69(8)
L. Balogh
K.S. Laverdure
S.P. Gido
A.G. Mott
M.J. Miller
B.P. Ketchel
D.A. Tomalia
Preparation of Novel Hollow Fiber Silica Using an Organic Gel as a Template
77(6)
Y. Ono
J. Hojo
S. Shinkai
A Silicon, Carbon and Deuterium NMR Investigation of Molecular Templating in Amorphous Silicas
83(6)
R.A. Assink
C.A. Click
T.M. Alam
C.J. Brinker
S.J. Naik
Thermosetting Mechanism Study of Organosilicon Polymer Containing Carborane by Solid-State NMR Spectroscopy
89(4)
H. Kimura
K. Okita
M. Ichitani
M. Yonezawa
T. sugimoto
Carborane-Siloxane-Diacetylene Thermosets and Ceramic Precursors
93(6)
J.P. Armistead
E.J. Houser
D.Y. Son
T.M. Keller
Dialkylenecarbonate-Bridged Polysilsesquioxanes: Hybrid Organic-Inorganic Sol-Gels With a Thermally Labile Bridging Group
99(6)
D.A. Loy
J.V. Beach
B.M. Baugher
R.A. Assink
K.J. Shea
J. Tran
J.H. Small
Porosity in Polysilsesquioxane Xerogels
105(6)
B.M. Baugher
D.A. Schneider
D.A. Loy
K. Rahimian
Controlled Cleavage of Fully-Condensed Silsesquioxane Frameworks: A Revolutionary New Method for Manufacturing Precursors to Hybrid Inorganic/Organic Materials
111(6)
F.J. Feher
D. Soulivong
Composition-Structure Relations in Organically Modified Silica Gels
117(12)
N. Husing
U. Schubert
Phosphazene Backbones for Siloxanes and Organic Polymers
129(8)
G. Kickelbick
P.J. Miller
K. Matyjaszewski
PART II: NOVEL ORDERED HYBRID STRUCTURES, LAYERED STRUCTURES AND ORGANIC MONOLAYERS
Melt Intercalation of PMMA into Organically-Modified Layered Silicate
137(6)
Z. Shen
G.P. Simon
Y-B. Cheng
Calculating Phase Diagrams of Polymer-Clay Mixtures by Combining Density Functional and Self-Consistent Field Theory
143(6)
A.C. Balazs
C. Singh
V.V. Ginzburg
Self-Assembly of Meso- and Nanoparticles into 3-D Ordered Arrays and Its Applications
149(6)
B. Gates
Y. Xia
Formation of Mesoscopic Polymer Dots by Rubbing Transfer
155(4)
M. Sano
J. Okamura
S. Shinkai
Superlattices of Semiconductor Quantum Size Particles In Layered Organic Acids
159(6)
R. Popovitz-Biro
S. Guo
V. Hensel
E. Shavit
M. Lahav
Stability of Self-Assembled Organic-Inorganic Layered Perovskite
165(6)
N. Kitazawa
T. Yamamoto
Y. Watanabe
Y. Nakamura
Covalent Attachment of a Single Dextran Polymer Between the Tip of an Atomic Force Microscope and a Gold Surface
171(6)
M. Grandbois
R. Decor
M. Rief
A. Wagner
C. Mioskowski
H. Gaub
Integrating Organic Molecules to Silicon Surfaces
177(6)
X-Y Zhu
J.A. Mulder
R.P. Hsung
W.F. Bergerson
A. Gasser
A. Nguyen
Self-Assembled Monolayers Derived from Bidentate Organosulfur Adsorbates
183(8)
Y-S. Shon
N. Garg
R. Colorado Jr.
R.J. Villazana
T.R. Lee
PART III: NON-SILICATE HYBRID MATERIALS
Selective Depositions of Fe-Containing Oxide Films on Mixed Self-Assembled Organic Monolayers Using Microcontact Printing
191(6)
H. Shin
H. Im
S. Hong
K. Lee
G. Lim
J.U. Jeon
E.S. Kim
Y.E. Pak
Synthesis and Characterization of Titania and Vanadia Thin Films at Organic Self-Assembled Monolayers
197(6)
T.P. Niesen
J. Wolff
J. Bill
M.R. De Guire
F. Aldinger
Deposition of Nanocrystalline Tin (IV) Oxide Films on Organic Self-Assembled Monolayers
203(6)
S. Supothina
M.R. De Guire
T.P. Niesen
J. Bill
F. Aldinger
A.H. Heuer
Synthesis of TiO2 Meso-Structured Thin Films
209(4)
H.S. Zhou
I. Honma
A New Route to Prepare Hard and Anti-Scratching Coatings at Room Temperature
213(8)
Y. Liu
R.O. Claus
A. Rosidian
T. Zeng
Formation and Hydrolytic Stability of Oxygen Bridged Heterometal Bonds (Si-O-Ti, Si-O-Zr, Si-O-Ta) in Sol-Gel Materials
221(8)
M. Nacken
D. Hoebbel
H. Schmidt
PART IV: MESO-, MICRO- AND MACROPOROUS HYBRIDS
One-Pot Synthesis of a Cubic Silicate Phase Functionalized With Phenyl Groups
229(6)
V. Goletto
V. Dagry
F. Babonneau
Thermal Stability of Structurally Controlled Lamellae and Hexagonal Mesoporous Silicate Thin Films
235(6)
I. Honma
A. Endo
D. Kundu
and H.S. Zhou
Siliceous Mesostructured Cellular Foams With Uniformly Sized and Shaped Pores
241(6)
P. Schmidt-Winkel
W.W. Lukens Jr.
D. Zhao
P. Yang
B.F. Chmelka
G.D. Stucky
Synthesis and Texture of Mesophase Templated Silica Layers Seeded With Nanoparticles
247(10)
M. Klotz
A. Ayral
A. Van der Lee
C. Guizard
C. Menager
V. Cabuil
PART V: HYBRID ELECTROCHEMISTRY PHOTOCHEMISTRY, AND PASSIVATION
Protonic Conducting Properties of Sol-Gel Derived Organic/Inorganic Nanocomposites Membrane Doped With Acidic Functional Molecules
257(6)
I. Honma
Y. Takeda
J.M. Bae
Nanostructural Lithography via Photo-Initiated Phase Transformation of Silica-Surfactant Assemblies
263(6)
D.A. Doshi
N. Husing
H. Fan
A.J. Hurd
C.J. Brinker
Sol-Gel Synthesis and Characterization of Molybdenum Oxide/Polypyrrole Hybrids
269(6)
W. Dong
B. Dunn
In Situ Intercalation/Polymerization of Melanin Into Vanadium Pentoxide
275(6)
H.P. Oliveria
C.L.P.S. Zanta
A.C. Galina
C.F.O. Graeff
Modifications of Preceramic Polymers Suitable for Corrosion Resistant and High Temperature Coatings
281(6)
Y.D. Blum
H.P. Chen
D. B. MacQueen
S.M. Johnson
Host-Guest Systems in the Development of Anticorrosive Polymeric Films
287(6)
L.R.M. Estevao
R.S.V. Nascimento
Synthesis of Hybrid Organic-Inorganic Sol-Gel Coatings for Corrosion Resistance
293(8)
T.L. Metroke
R.L. Parkhill
E.T. Knobbe
PART VI: MECHANICAL PROPERTIES AND APPLICATIONS
Mechanical Properties of Low Dielectric-Constant Organic-Inorganic Hybrids
301(12)
R.F. Cook
Effect of Curing Strategies on Porosity in Silane-Modified Silica Colloidal Coatings
313(6)
M.W. Daniels
L.F. Francis
Organic/Inorganic Hybrid Sol-Gel Derived Hard Coatings on Plastics
319(6)
C.M. Chan
G.Z. Cao
H. Fong
M. Sarikaya
T. Robinson
L. Nelson
Nanoscaled Filled Sol-Gel Hybrid Materials for Powder Coatings
325(6)
S. Sepeur
C. Dittfurth
J. Muhle
A. Poppe
H. Schmidt
Tear Strengths of Poly(dimethylsiloxane) Networks Reinforced With In Situ Precipitated Silica
331(6)
C. Kumudinie
J.E. Mark
Mechanical Properties of Soluble Polymer/Silica Gel Hybrids
337(6)
L.C. Klein
J. Van Wert
C.L. Beaudry
Viscoelastic Responses of Inorganic-Organic Hybrids Polymers
343(8)
A. Lee
Preparation and Properties of PVC-Silica Composites Using Different Catalysts Via Sol-Gel Process
351(6)
K.M. Asif
M.I. Sarwar
Z. Ahmad
Synthesis-Morphology-Mechanical Properties Relationships of Polymer-Silica Nanocomposite Hybrid Materials
357(6)
P. Hajji
L. David
J.F. Gerard
H. Kaddami
J.P. Pascault
G. Vigier
Materials With Improved Properties From Polymer-Ceramic Nanocomposites
363(8)
F-D. Kuchta
P.J. Lemstra
A. Keller
L.F. Batenburg
H.R. Fischer
PART VII: BIOMEDICAL, ELECTRONIC AND OPTICAL APPLICATIONS OF HYBRID MATERIALS
High Surface Area Substrates for DNA Arrays
371(6)
M. Glazer
C. Frank
R.P. Vinci
G. McGall
J. Fidanza
J. Beecher
Surface Modification of Polymers With Grafting and Coating of Silane Hybrids and Their Bioactivity
377(6)
M. Kubo
S. Takashima
K. Tsuru
S. Hayakawa
A. Osaka
C. Ohtsuki
Lowering the Percolation Threshold in Carbon Black-Filled Polymer Composites
383(6)
J.C. Grunlan
W.W. Gerberich
L.F. Francis
Electronic Properties of the Model Organometallic Polymer (M-C=C(N)2 (M = Cu(I), Ag(I), Au(I))
389(6)
Z.M. Su
R.S. Wang
C.M. Che
Organic-Inorganic Hybrid Materials Processing and Applications
395(14)
H.K. Schmidt
M. Mennig
R. Nonninger
P.W. Oliveira
H. Schirra
Photochromic Organic-Inorganic Hybrid Nanocomposite Hard Coatings With Tailored Fast Switching Properties
409(6)
M. Mennig
K. Fries
H. Schmidt
Sol-Gel NIR-Reflective Multilayer Coatings on Glass Through UV-Polymerizable Ceramic Nanoparticles
415(6)
M. Mennig
P.W. Oliveria
H. Schmidt
Fabrication of GRIN-Lenses by Contactless Electrophoretic-Gradient Formation in Transparent Nanocomposites
421(6)
P.W. Oliveira
M. Mennig
H. Schmidt
Sol-Gel Derived Titania/Ormosil Composite Thin Films for Optical Waveguide Applications
427(6)
W. Que, Y. Zhou
Y.L. Lam
Y.C. Chan
S.D. Cheng
C.H. Kam
H.X. Zhang
Synthesis and Characterization of Optically-Active Lanthanide-Doped Hybrid Inorganic-Organic Systems
433(6)
R.E. Taylor-Smith
K.M. Choi
Inorganic Quantum Dot-Organic Dendrimer Nanocomposite Materials
439(6)
K. Sooklal
J. Huang
C.J. Murphy
L. Hanus
H.J. Ploehn
Optical Characteristics of Silica-Poly(ethylene oxide) Hybrid Thin Films
445(6)
O.H. Park
Y.J. Eo
Y.K. Choi
B.S. Bae
Influence of Hybridation With a Silicate Network on the Properties of an Eu3+ Complex Derived From Dipicolinic Acid
451(8)
A.C. Franville
D. Zambon
R. Mahiou
Y. Troin
J.C. Cousseins
Author Index 459(4)
Subject Index 463

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