Supramolecular Chemistry, 8 Volume Set From Molecules to Nanomaterials

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Edition: 1st
Format: Hardcover
Pub. Date: 2012-03-05
Publisher(s): Wiley
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Summary

Supramolecular Chemistry: From Molecules to Nanomaterials is a new major reference work which links supramolecular chemistry and nanomaterials. Presenting over 160 tutorial articles and spanning over 10 comprehensive sections, this new resource covers: Concepts Techniques Molecular recognition Supramolecular reactivity Supramolecular aspects of chemical biology Self processes Supramolecular devices Supramolecular materials chemistry Soft matter Nanotechnology Supramolecular chemistry is ''chemistry beyond the molecule''. While traditional chemistry focuses on the bonds that hold atoms together in a molecule, supramolecular chemistry examines the weaker interactions that hold groups of molecules together. Important concepts that have been demonstrated by supramolecular chemistry include molecular self-assembly, folding, molecular recognition, host-guest chemistry, mechanically-interlocked molecular architectures, and dynamic covalent chemistry. The importance of supramolecular chemistry was established by the 1987 Nobel Prize for Chemistry, which was awarded to Donald J. Cram, Jean-Marie Lehn, and Charles J. Pedersen in recognition of their work in the field. The past decade has seen dramatic developments in the field, with supramolecular chemistry leaving its roots in classical host guest chemistry and expanding into exciting areas of materials chemistry and nanoscience with many real and potential applications. Supramolecular findings are evolving our understanding of the way chemical concepts at the molecular level build up into materials and systems with fascinating, emergent properties on the nanoscale. Supramolecular chemistry: the biggest challenge yet! "Creating that link between the chemist''s understanding of the way in which molecules interact with one another, and the understanding a materials scientist, engineer or biologist has of the resulting properties of a material or system comprised of those molecules is one of the huge grand challenges facing modern molecular science." - Philip A. Gale and Jonathan W. Steed, Editors-in-Chief Linking supramolecular chemistry and nanotechnology to define the field in the 21st Century... Supramolecular Chemistry: From Molecules to Nanomaterials is the first major reference to link supramolecular chemistry and nanotechnology. A global team of experts present an overview of the concepts and techniques of modern supramolecular chemistry, demonstrating how these paradigms evolve into nanoscale systems chemistry, nanotechnology, materials science and beyond. Breaking down the barriers between synthetic chemistry and materials science, the authors demonstrate how modern techniques allow access increasingly far along the ''synthesising-up'' pathway. Supramolecular Chemistry: From Molecules to Nanomaterials explains the fundamental concepts and provides invaluable practical guidance on the applications and limitations of modern instrumental techniques for addressing molecular and materials-based problems. The printed edition of Supramolecular Chemistry: From Molecules to Nanomaterials is available as an eight-volume set. Publishing in full colour to enhance the interpretation of complex supramolecular structures the printed edition is highly illustrated with an average of three images per page features fully indexed articles with cross-references integrated into the text includes a glossary of key terms Introductory Offer! Order the printed edition of Supramolecular Chemistry: From Molecules to Nanomaterials before 30th April 2012 and take advantage of the special introductory price: 1275.00/ 1640.00/$1995.00. Prices will revert to 1595.00/ 2050.00/$2495.00 thereafter. Online Edition Supramolecular Chemistry: From Molecules to Nanomaterials will also be availabe online from March 2012.

Author Biography

Editors-in-Chief
Professor Philip Gale, School of Chemistry, University of Southampton,UK
Professor Gale is currently Head of the School of Chemistry at Southampton University. He is the author or co-author of over 160 publications including two books and a series of highly cited review articles on anion complexation. Professor Gale has won a number of research prizes and is the co-editor of the journal Supramolecular Chemistry, a commissioning editor for Chemical Society Reviews and a member of the international editorial advisory boards of Coordination Chemistry Reviews, the Encyclopaedia of Supramolecular Chemistry, The Open Inorganic Chemistry Journal and Chemical Communications. Professor Gale is also a member of RSC Science Policy Board.

Professor Jonathan Steed, Professor of Inorganic Chemistry, Department of Chemistry, Durham University,UK
Jonathan Steed is Professor of Inorganic Chemistry at Durham University. He is co-author of the textbooks Supramolecular Chemistry (2000 & 2009), Core Concepts in Supramolecular Chemistry and Nanochemistry (2007) and around 250 research papers. He has edited the Encyclopaedia of Supramolecular Chemistry (2004) and Organic Nanostructures (2008).

International Advisory Board
Jerry Atwood - University of Missouri-Columbia
Paul D. Beer - University of Oxford
Makoto Fujita - The University of Tokyo
Tom Fyles - University of Victoria
Andrew D. Hamilton - Yale University
Michaele Hardie - University of Leeds
Ivan Huc - Institut Européen de Chimie et Biologie (IECB)
Yun-Bao Jiang - Xiamen University
Kate Jolliffe - The University of Sydney
Kimoon Kim - Pohang University of Science and Technology (POSTECH)
David A. Leigh - University of Edinburgh
Jonathan L. Sessler - Institute for Cellular and Molecular Biology
George Shimizu - University of Calgary

Section Editors
Philip Gale, University of Southampton, UK
Eric Anslyn, University of Texas, USA
Bradley Smith, University of Notre Dame, USA
Edwin Constable, University of Basel, Switzerland
Enrique García-España, Universidad de Valencia, Spain
Douglas Philp, University of St Andrews, UK
Marcey Waters, University of North Carolina, USA
David Amabilino, Institut de Ciencia de Materials de Barcelona (CSIC), Spain
Pavel Anzenbacher, Bowling Green State University, USA
Len Barbour, University of Stellenbosch, South Africa
David K Smith, University of York, UK
Paula Mendes & Jonathan Preece, University of Birmingham, UK Co

Table of Contents

Concepts
Contributors to Volume 1p. xiii
Forewordp. xv
Prefacep. xvii
Abbreviations and Acronymsp. xix
Concepts 1 Definition and Emergence of Supramolecular Chemistryp. 3
Supramolecular Interactionsp. 9
Complementarity and Preorganizationp. 25
The Thermodynamics of Molecular Recognitionp. 45
Cooperativity and the Chelate, Macrocyclic and Cryptate Effectsp. 67
Multivalencyp. 95
Solvation Effects in Supramolecular Recognitionp. 117
Competition Experimentsp. 135
Supramolecular Information/Programming from a Boolean Perspectivep. 161
Self-Assembly and Self-Organizationp. 167
Introduction to Surfactant Self-Assemblyp. 181
Reversible Covalent Bond Toolboxp. 205
Chiralityp. 217
Techniques
Contributors to Volume 2p. xiii
Forewordp. xvii
Prefacep. xix
Abbreviations and Acronymsp. xxi
Techniquesp. 237
Binding Constants and Their Measurementp. 239
Isothermal Titration Calorimetry in Supramolecular Chemistryp. 275
NMR Spectroscopy in Solutionp. 297
Diffusion Ordered NMR Spectroscopy (DOSY)p. 319
Solid-State NMR Studies on Supramolecular Chemistryp. 331
Mass Spectrometry and Gas-Phase Chemistry of Supermolecules: A Primerp. 347
Luminescent Spectroscopy in Supramolecular Chemistryp. 379
Circular Dichroism Spectroscopyp. 393
Dynamic Light Scattering in Supramolecular Materials Chemistryp. 411
X-Ray Diffraction: Addressing Structural Complexity in Supramolecular Chemistryp. 425
Small-Angle X-ray Scattering (SAXS) and Wide-Angle X-ray Scattering (WAXS) of Supramolecular Assembliesp. 437
Supramolecular Electrochemistryp. 451
Transport Experiments in Membranesp. 473
Vesicles in Supramolecular Chemistryp. 501
Rheologyp. 517
Langmuir-Blodgett Filmsp. 529
Affinity Capillary Electrophoresis as a Tool to Characterize Intermolecular Interactionsp. 543
Ion Chromatography and Membrane Separations Using Macrocyclic Ligandsp. 563
Brewster Angle Microscopyp. 589
Scanning Electron Microscopyp. 619
Transmission Electron Microscopy (TEM)p. 633
Scanning Tunneling Microscopy (STM)p. 647
Atomic Force Microscopy (AFM)p. 659
Scanning Near-Field Optical Microscopy (SNOM)p. 669
Computational Techniques (DFT, MM, TD-DFT, PCM)p. 689
Uses of Differential Sensing and Arrays in Chemical Analysisp. 709
Molecular Recognition
Contributors to Volume 3p. xiii
Forewordp. xv
Prefacep. xvii
Abbreviations and Acronymsp. xix
Molecular Recognitionp. 731
Crown and Lariat Ethersp. 733
Azacycloalkanes and Azacyclophanesp. 753
Hetero-Crown Ethers-Synthesis and Metal-Binding Properties of Macrocyclic Ligands Bearing Group 16 (S, Se, Te) Donor Atomsp. 785
Cryptands and Spherandsp. 811
Schiff Base and Reduced Schiff Base Ligandsp. 827
Calixarenes in Molecular Recognitionp. 863
Cyclotriveratrylene and Cryptophanesp. 895
Carcerands and Hemicarcerandsp. 917
Cyclodextrins: From Nature to Nanotechnologyp. 955
Cucurbituril Receptors and Drug Deliveryp. 983
Podandsp. 1001
Porphyrins and Expanded Porphyrins as Receptorsp. 1045
Supramolecular Phthalocyanine-Based Systemsp. 1075
Guanidinium-Based Receptors for Oxoanionsp. 1101
Anion Receptors Containing Heterocyclic Ringsp. 1125
Amide and Urea-Based Receptors, MD. Alamgir Hossainp. 1153
Synthetic Peptide-Based Receptorsp. 1179
Biological Small Molecules as Receptorsp. 1205
Receptors for Nucleotidesp. 1225
Receptors for Zwitterionic Speciesp. 1259
Ion-Pair Receptorsp. 1281
Metal Complexes as Receptorsp. 1309
Hydrogen-Bonding Receptors for Molecular Guestsp. 1325
Boronic Acid-Based Receptorsp. 1345
Supramolecular Catalysis, Reactivity And Chemical Biology
Contributors to Volume 4p. xiii
Forewordp. xvii
Prefacep. xix
Abbreviations and Acronymsp. xxi
Supramolecular Reactivityp. 1381
Supramolecular Organocatalysisp. 1383
Replication Processes-From Autocatalysis to Systems Chemistryp. 1415
Artificial Enzyme Mimicsp. 1447
Dynamic Covalent Chemistryp. 1497
Reaction Networksp. 1527
Reactions in Dynamic Self-Assembliesp. 1543
Reactivity in Nanoscale Vesselsp. 1575
Reactions in Solid-State Inclusion Compoundsp. 1589
Functional Polymersp. 1613
Supramolecular Aspects of Chemical Biologyp. 1637
Rational Design of Peptide-Based Biosupramolecular Systemsp. 1639
Nucleic Acid Mimeticsp. 1665
Supramolecular Approaches to the Study of Glycobiologyp. 1685
Porphyrinoids: Highly Versatile, Redox-Active Scaffolds for Supramolecular Design and Biomimetic Applicationsp. 1713
Supramolecular Chemistry of Membranesp. 1731
Membrane Transportp. 1751
Supramolecular Bioinorganic Chemistryp. 1771
The Role of Supramolecular Chemistry in Responsive Vectors for Gene Deliveryp. 1807
Supramolecular Chemistry in In Vitro
Biosensorsp. 1825
Supramolecular Chemistry in Biological Imaging In Vivop. 1851
Aptamer Moieties in Biochemical Applicationsp. 1877
Supramolecular Approaches for Inhibition of Protein-Protein and Protein-DNA Interactionsp. 1885
Supramolecular Approaches to Medicinal Chemistryp. 1909
Supramolecular Systems for Tissue Engineeringp. 1929
Chemical Biology Using Fluorinated Building Blocksp. 1947
Self-Assembly And Supramolecular Devices
Contributors to Volume 5p. xiii
Forewordp. xvii
Prefacep. xix
Abbreviations and Acronymsp. xxi
Self-Processesp. 1965
Template Strategies in Self-Assemblyp. 1967
Self-Assembly of Coordination Compounds: Design Principlesp. 1993
Self-Assembly of Coordination Chains and Helicesp. 2045
Self-Assembly of Coordination Cages and Spheresp. 2071
Self-Assembly of Organic Supramolecular Capsulesp. 2085
Self-Assembly of Supramolecular Wiresp. 2115
Synthesis of Supramolecular Nanotubesp. 2149
Organic Foldamers and Helicesp. 2183
Self-Assembly of Macromolecular Threaded Systemsp. 2207
Self-Assembled Links: Catenanesp. 2225
Templated Synthesis of Knots and Ravelsp. 2245
Self-Assembly of Nucleic Acidsp. 2263
Viruses as Self-Assembled Templatesp. 2275
Peptide Self-Assemblyp. 2293
Rotaxanes-Self-Assembled Linksp. 2311
Supramolecular Devicesp. 2331
Photoprocesses of Relevance to Supramolecular Chemistryp. 2333
Photoinduced Electron Transfer Processes in Biological and Artificial Supramoleculesp. 2365
Molecular Devices: Energy Transferp. 2397
Molecular Devices: Molecular Machineryp. 2425
Molecular Logic Gatesp. 2497
Single-Molecule Electronicsp. 2507
Molecular Redox Sensorsp. 2523
Ion-Selective Electrodes With Ionophore-Doped Sensing Membranesp. 2539
Colorimetric Sensorsp. 2581
Luminescent Sensingp. 2611
Photoswitching Materialsp. 2643
Supramolecular Chemistry in Medicinep. 2675
Magnetic Resonance Imaging Contrast Agentsp. 2693
Supramolecular Chemistry for Organic Photovoltaicsp. 2725
Supramolecular Materials Chemistry
Contributors to Volume 6p. xiii
Forewordp. xv
Prefacep. xvii
Abbreviations and Acronymsp. xix
Supramolecular Materials Chemistryp. 2789
Crystal Engineeringp. 2791
Noncovalent Interactions in Crystalsp. 2829
Concepts and Nomenclature in Chemical Crystallographyp. 2869
Crystal Structure Predictionp. 2905
The Cambridge Structural Database System and Its Applications in Supramolecular Chemistry and Materials Designp. 2927
Crystal Growth and Molecular Crystal Growth Modificationp. 2947
Polymorphism: Fundamentals and Applicationsp. 2957
Cocrystals: Synthesis, Structure, and Applicationsp. 2975
Mechanical Preparation of Crystalline Materials. An Oxymoron?p. 2993
Physico-Chemical Aspects of Inclusion Compoundsp. 3009
Clathrate Hydratesp. 3017
Synthetic Clathrate Systemsp. 3033
Network and Graph Set Analysisp. 3057
Coordination Polymersp. 3073
Zeolitelike Metal-Organic Frameworks (ZMOFs): Design, Structure, and Propertiesp. 3087
Interpenetrationp. 3107
Supramolecular Isomerismp. 3121
Gas Storage and Separation in Supramolecular Materialsp. 3133
Templated [2 + 2] Photodimerizations in the Solid Statep. 3153
Soft Matter
Contributors to Volume 7p. xiii
Forewordp. xv
Prefacep. xvii
Abbreviations and Acronymsp. xix
Soft Matterp. 3167
Soft Matter Science-a Historical Overview with a Supramolecular Perspectivep. 3169
Multicomponent Self-Assembled Polymers Based on ¿-Conjugated Systemsp. 3183
Functions Based on Dynamic Structural Changes of Coordination Polymersp. 3205
Self-Healing and Mendable Supramolecular Polymersp. 3221
Assembly of Block Copolymersp. 3235
Molecularly Imprinted Polymersp. 3255
Supramolecular Dendrimer Chemistryp. 3283
Hyperbranched Polymers in Supramolecular Chemistryp. 3297
Supramolecular Chemistry in Polymer Networksp. 3321
Stimuli-Responsive and Motile Supramolecular Soft Materialsp. 3337
Self-Assembling Fibrillar Networks-Supramolecular Gelsp. 3355
Self-Assembly of Facial Amphiphiles in Waterp. 3377
Self-Assembly of Surfactants at Solid Surfacesp. 3395
Physisorption for Self-Assembly of Supramolecular Systems: A Scanning Tunneling Microscopy Perspectivep. 3419
Chemisorbed Self-Assembled Monolayersp. 3445
Self-Organization and Self-Assembly in Liquid-Crystalline Materialsp. 3463
Liquid Crystals Formed from Specific Supramolecular Interactionsp. 3493
Covalent Capture of Self-Assembled Soft Materialsp. 3515
Designing Peptide-Based Supramolecular Biomaterialsp. 3525
Self-Assembly of Polymers into Soft Nanoparticles and Nanocapsulesp. 3541
Self-Assembled Polymer Supermolecules as Templates for Nanomaterialsp. 3563
Nanotechnology
Contributors to Volume 8p. xiii
Forewordp. xv
Prefacep. xvii
Abbreviations and Acronymsp. xix
Nanotechnologyp. 3587
Nanotechnology: The "Top-Down" and "Bottom-Up" Approachesp. 3589
Nanolithographyp. 3603
Two-Dimensional Supramolecular Chemistryp. 3625
Biologically Derived Supramolecular Materialsp. 3647
Supramolecular Hybrid Nanomaterials as Prospective Sensing Platformsp. 3669
Self-Assembled Nanoparticlesp. 3699
Photochemically Driven Molecular Devices and Machinesp. 3719
Magnetically Responsive Self-Assembled Composite Materialsp. 3751
Advances in Supramolecular Chemistry of Carbon Nanotubesp. 3767
One-Dimensional Nanostructures of Molecular Graphenesp. 3791
Supramolecular Nanoparticles for Molecular Diagnostics and Therapeuticsp. 3809
Atomic Force Microscopy Measurements of Supramolecular Interactionsp. 3825
Nanoelectronicsp. 3841
Glossaryp. 3859
Subject Indexp. 3887
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